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1. G. R. Desiraju / Review of General Principles in Comprehensive Supramolecular
Chemistry . 1996. Vol. 6.-Elsevier, Amsterdam.
2. Braga D., Grepioni F. and Desiraju G. / Crystal engineering and
organometallic architecture .// Chem. Rev. 1998. Vol. 98. P. 1375-1405.
3. Hyunuk Kim , Sunirban Das , Min Gyu Kim , Danil N. Dybtsev , Yonghwi
Kim , and Kimoon Kim / Synthesis of Phase-Pure Interpenetrated MOF-5 and
Its Gas Sorption Properties. // Inorg. Chem.. 2011. Vol. 50 (8). P. 3691
3696.
4. Chen, X; Ye, B., Tong, M. / Metal-organic molecular architectures with 2,2′-
bipyridyl-like and carboxylate ligands. // Coord. Chem. Rev. 2005.
Vol. 249. P. 545565.
5. Cote, A; Shimizu, G. / Coordination Solids via Assembly of Adaptable
Components : Systematic Structural Variation in Alkaline Earth
Organosulfonate Networks // Chem. Eur. J. 2003. Vol.9. P. 53615370.
6. Keller, S.; Knaust, J. A / Mixed-Ligand Coordination Polymer from the in
Situ, Cu(I)-Mediated Isomerization of Bis(4-pyridyl)ethylene. // Inorg.
Chem.. 2002. Vol. 41 (22). P. 56505652.
7. Ni LB, Zhang RH, et al. / pH- and mol-ratio dependent formation of zinc(II)
coordination polymers with iminodiacetic acid: Synthesis, spectroscopic,
crystal structure and thermal studies. // J. Of Sol. Stat. Chem. 2009.
Vol. 182. P. 26982706.
8. Rizzato, Silvia; Carlucci, Ciani, Proserpio / New polymeric networks from the
self-assembly of silver(I) salts and the flexible ligand 1,3-bis(4-
pyridyl)propane (bpp). A systematic investigation of the effects of the counter
ions and a survey of the coordination polymers based on bpp. // Cryst. Eng.
Comm. 2002. Vol. 4. P. 121-129.
99
9. I. Boldog, E.B. Rusanov, J. Sieler, K.V. Domasevitch / Cooperative
association of pyrazoles and phenols: A versatile binary system. // New J.
Chem. 2004. Vol. 28. P. 756-759.
10. B.F. Abrahams, B.F. Hoskins, G. Winter / The structure of cadmium
bis(isopropylxanthate)-4,4-bipyridine. // Aust. J. Chem. 1990. Vol. 43 (10)
P. 17591765.
11. Roesky, Herbert W., Andruh, Marius / The interplay of coordinative, hydrogen
bonding and p-p stacking interactions in sustaining supramolecular solid-state
architectures. A study case of bis(4-pyridyl)- and bis(4-pyridyl-N-oxide) tectons.
// Coord.Chem. Rev. 2003. Vol. 236(1-2). P. 91-119.
12. Rüdiger W. Seidel, Richard Goddard, Bodo Zibrowius and Iris M. Oppel / A
Molecular Antenna Coordination Polymer from Cadmium(II) and 4,4-Bipyridine
Featuring Three Distinct Polymer Strands in the Crystal. // Polymers. 2011.
Vol.3. P. 1458-1474.
13. K. Nicole Power, Tracy L. Hennigar and Michael J. Zaworotko / Crystal structure
of the coordination polymer [Co(bipy)1.5(NO3)2]CS2(bipy=4,4′-bipyridine), a new
motif for a network sustained by ‗T-shape building blocks. // New J. Chem..
1998. Vol. 22. P. 177-181.
14. Biradha, A. Mondal, B. Moulton, M. J. Zaworotko / Coexisting covalent and noncovalent
planar networks in the crystal structures of
{[M(bipy)2(NO3)2]arene}n (M = Ni, 1; Co, 2; arene = chlorobenzene, odichlorobenzene,
benzene, nitrobenzene, toluene or anisole). // Dalton Trans.
2001. Vol.9 P. 3837-3844.
15. L. R. MacGillivray, S. Subramanian, M. J. Zaworotko / Interwoven Two- and
Three-dimensional Coordination Polymers Through Self-assembly of Cu(I)
Cations with Linear Bidentate Ligands. // J. Chem. Soc., Chem.Commun. 1994.
Vol.11. P. 1325-1326.
16. Gareth R. Lewis and A. Guy Orpen / A metal-containing synthon for crystal
engineering: synthesis of the hydrogen bond ribbon polymer [4,4-H2bipy][MCl4 ]
(M = Pd, Pt). // Chem. Commun. 1998. Vol.17. P. 1873-1874.
100
17. Amy L. Gillon,Gareth R. Lewis, A. Guy Orpen, Sarah Rotter, Jonathan Starbuck,
Xi-Meng Wang, Yolanda Rodrígue z-Martín and Catalina Ruiz-Pérez / Organic
inorganic hybrid solids: control of perhalometallate solid state structures . // J.
Chem. Soc., Dalton Trans. 2000. Vol.21. P. 38973905.
18. Yu-Cang Liang, Mao-Chun Hong, Rong Cao, Wei-Ping Su, Ying-Jun Zhao, Jia-
Bao Weng / Infinite chain structures of [Zn(4,4-bipy)Cl2]n and [Cu(H2PO4)(4,4-
bipy)2H2O]n via hydrothermal synthesis. // Polyhedron. 2001. Vol. 20.
24772481.
19. Jeyagowry T. Sampanthar and Jagadese J. Vittal / Reaction of Cd(NO3)2 4H2O
with 4,4-bipyridine (bpy) in MeOH solvent: synthesis and characterization of Tshaped
[Cd(bpy)1.5(NO3)2]3H2O, square grid [Cd(bpy)2(H2O)2](NO3)24H2O and
linear polymeric [Cd(bpy)(H2O)2(NO3)2. // Crystal Engineering. 1999. Vol.
2(4). P. 251264.
20. C.-Y. Zhang, X.-J. Yao, R.-L. Wang and C.-Z. Xie / Poly[[bis( -4,4'-bipyridine-
2N:N')copper(I)] perchlorate 0.24-hydrate] // Acta Cryst. 2012. E68.
m660m661.
21. V. R. Pedireddi, Manishkumar R. Shimpi, J. V. Yakhmi / Room-Temperature
Ionic Liquids: For a Difference in the Supramolecular Synthesis. // Macromol.
Symp. 2006. Vol. 241. P. 8387.
22. O. M. Yaghi and Guangming Li / Mutually Interpenetrating Sheets and Channels
in the Extended Structure of [Cu(4,4'-bpy)Cl]. // Angew. Chem. Int . Ed. Engl.
1995. Vol. 34(2). P.207-209.
23. Ishtvan Boldog,, Jean-Claude Daran, Alexander N. Chernega, Eduard B. Rusanov,
Harald Krautscheid, and Konstantin V. Domasevitch / Hydrogen Bonding Patterns
and Supramolecular Structure of 4,4′-Bipyrazolium Salts. // Cryst. Growth Des.
2009. Vol. 9 (6). P. 28952905.
24. Ishtvan Boldog a, Joachim Sielerb, Alexander N. Chernega c, KonstantinV.
Domase vitc h / 4,4-Bipyrazolyl: new bitopic connector for construction
ofcoordination networks. // Inorganica Chimica Acta . 2002. Vol. 338. P. 69
77.
25. Aurel Tabacaru, Claudio Pettinari, Fabio Marchetti,Corrado di Nicola, Konstantin
V. Domasevitch, Simona Galli, Norberto Masciocchi, Stefania Scuri, Iolanda
101
Grappasonni, and Mario Cocchioni /Antibacterial Action of 4,4′-Bipyrazolyl-
Based Silver(I) Coordination Polymers Embedded in PE Disks. // Inorg. Chem.
2012. Vol.51. 9775−9788.
26. Claudio Pettinari, Aurel Tabacaru, Ishtvan Boldog, Konstantin V. Domasevitch,
Simona Galli, and Norberto Masciocchi / Novel Coordination Frameworks
Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand. // Inorg. Chem. 2012. 51.
P. 5235−5245.
27. Qing-Fu Sun, Keith Man-Chung Wong, Li-Xia Liu, Hai-Ping Huang, Shu-Yan
Yu,Vivian Wing-Wah Yam,Yi-Zhi Li, Yuan-Jiang Pan, and Kai-Chao Yu / Self-
Assembly, Structures, and Photophysical Properties of 4,4′-Bipyrazolate-Linked
Metallo-Macrocycles with Dimetal Clips. // Inorg. Chem. 2008. Vol. 47(6). p.
2142-2154.
28. D. Braga, F. Grepioni./ Complementary hydrogen bonds and ionic interactions
give access to the engineering of organometallic crystals. // J. Chem. Soc., Dalton
Trans. 1999. P.18.
29. I. Boldog, E.B. Rusanov, J. Sieler, S. Blaurock, K.V. Domasevitch / Construction
of extended networks with a trimeric pyrazole synthon. // Chem. Commun.
2003. P. 740-741.
30. G. Yang, R.G. Raptis, P. Šafar / Cadmium( II) complexes of 4 -(4-pyridyl)pyrazole:
A case of two conformational supramolecular isomers polythreaded in the same
crystal and a rare example of 5-connected nov net. // Cryst. Growth Des. 2008.
Vol.8 (3). P. 981985.
31. Y. Mulyana, C.J. Kepert, L.F. Lindoy, A. Parkin, P. Turner / New cobalt(II) and
zinc(II) coordination frameworks incorporating a pyridyl -pyrazole ditopic ligand.
// Dalton Trans. 2005. P. 1598-1601.
32. Jin Tong, Shu-Yan Yu and Hui Li / Programmable self-assembly of homo- or
hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine. / Chem.
Commun. 2012. Vol. 48. P. 53435345.
33. Lei Hou,Wen-Juan Shi,Yao-Yu Wang, Hai-Hua Wang, Lin Cui, Peng-Xiang
Chen, and Qi-Zhen Shi / Trinuclear-based Copper(I) Pyrazolate Polymers: Effect
of Trimer π-AcidHalide/Pseudohalide Interactions on the
102
SupramolecularStructure and Phosphorescence. // Inorg. Chem. 2011. Vol.
50(1). P.261 270.
34. Wei Wei, Kai Yu, Zhan-hua Su, Yang Yu, Bai-bin Zhou, Chun-cheng Zhu / A
novel copper molybdate inorganicorganic hybrid network synthesized by in-situ
generation of pyridine-4-carboxylic ion from 1,3-bis(4-pyridyl) propane precursor.
// Inorg. Chem. Comm. 2012. Vol. 17. P. 2125.
35. Pamela J. Zapf, Robert C. Haushalter and Jon Zubieta / Crystal engineering of
inorganic/organic composite solids: the structure-directing role of aromatic
ammonium cations in the synthesis of the ‗step-layered molybdenum oxide phase
[4,4-H2bpy][Mo7O22]H2O. // Chem. Comm. 1997. P. 321-322.
36. V.V. Atuchin T.A. Gavrilova T.I. Grigorieva N.V. Kuratieva K.A. Okotrub N.V.
Pervukhina N.V. Surovtsev / Sublimation growth and vibrational
microspectrometry of α-MoO3 single crystals. // Journal of Crystal Growth. 2011.
Vol. 318. P. 987990.
37. Pamela J. Hagrman, Robert L. LaDuca, Jr., H.-J. Koo, Randy Rarig, Jr., Robert C.
Haushalter, Myung-Hwan Whangbo, and Jon Zubieta / Ligand Influences on the
Structures of Molybdenum Oxide Networks. // Inorg. Chem. 2000. Vol. 39.
P. 43114317.
38. Yiping Chena, Hanhui Zhanga , Xuezhen Wanga Changcang Huanga Yanning
Caoa Ruiqing Suna / Structure and two-dimensional correlation infrared
spectroscoscopy study of two isomeric forms of the octamolybdate cluster //
Journal of Solid State Chemistry. 2006. Vol. 179 P.16741680.
39. C.J.G. Garcia, E. Coronado, S. Triki, L. Ouahab, P.Delhaes / First
tetrathiafulvalene (TTF) cation-radical salt containing the inorganic
polyoxometalate β-[Mo8O26]4-. // Adv. Mater. 2003. Vol. 5(4). P.283285.
40. J. Lu, E.H. Shen, Y.G. Li, D.R. Xiao, E.B. Wang, L. Xu / A Novel Pillar-Layered
Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate
Clusters: New Opportunity toward the Design and Synthesis of Porous
Framework. // Cryst.Growth Des. 2005. Vol. 5(1). P. 6567.
41. Guo Ming-Lin, Li Hui-Zhen / Selective oxidation of benzyl alcohol to
benzaldehyde with hydrogen peroxide over tetra-alkylpyridinium octamolybdate
catalysts // Green Chem. 2007. Vol.9. P. 421-423.
103
42. Qi-Bing Bo , Zhong-Xi Sun , Guo-Xin Sun , Allan Holmgren / Simple Directed
Material Design Through in Situ Substitution of Proton with Cu+Ions. // J. Inorg.
Organomet. Polym. 2009. Vol. 19. P.485493.
43. Chuan-De Wu, Can-Zhong Lu, Hong-Hui Zhuang and Jin-Shun Huang / Bis [4,4-
bipyridinium(2+)] hexacosaoxooctamolybdate. // Acta Cryst. 2001. E57.
m349-m351.
44. Randy S. Rarig, Jr., Robert Lam, Peter Y. Zavalij, J. Katana Ngala, Robert L.
LaDuca, Jr.,John E. Greedan,and Jon Zubieta / Ligand Influences on Copper
Molybdate Networks: The Structures and Magnetism of [Cu(3,4 ′-bpy)MoO4],
[Cu(3,3′-bpy)0.5MoO4], and [Cu(4,4′-bpy)0.5MoO4] 1.5H2O. // Inorg. Chem.
2002. Vol. 41(8). P. 21242133.
45. Zuping Kong, Linhong Weng, Dejun Tan, Heyong He, Biao Zhang, Jilie Kong,
and Bin Yue / Hydrothermal Synthesis, Crystal Structure, Conductivity, and
Thermal Decomposition of [Cu(4,4′-bipy)(H2O)(Mo3O10)]H2O. // Inorg. Chem.
2004. Vol. 43(18). P. 5676-5680.
46. C. L. Wang et al. / Hydrothermal synthesis, crystal structure and fluorescence of a
3D organicinorganic hybrid coordination network [Cu (4,4-bipy)]4 [β-Mo8O26]
exhibiting an interesting polymorphism. // J. of Coord. Chem. 2008. Vol. 61(6).
P. 891899.
47. Catalina Ruiz-Peréz, Pablo Lorenzo-Luis, Marıá Hernánde z-Molina, M. Milagros
Laz, Fernando S. Delgado, Pedro Gili, and Miguel Julve /1,2,4,5-
Benzenetetracarboxylic Acid and 4,4-Bipyridine as Ligands in Designing Low-
Dimensional Coordination Polymers. // Eur. J. Inorg. Chem. 2004. P. 3873-
3879.
48. Xin-Hua Li,* Xin-Xiang Lei and Shun Wang / 4,4-Bipyridinium bis(3,5-
dicarboxybenzoate)benzene-1,3,5-tricarboxylic acid hexahydrate. // Acta Cryst.
2005. E61. o1802o1804.
49. Eun Young Choi and Young-Uk Kwon / Diversification of Hydrothermal Reaction
Products Induced by Naphthalene Molecules. // Inorg. Chem. 2005. Vol. 44(3).
P.538545.
104
50. Huan-Ran Xing, Xin-Hua Li and Qian Shi / Syntheses, structure and magnetism of
a new linear-chain coordination polymer [[Co(TMA)2(4,4-bipyridine)2]
H2O]n [TMA=Trimesate]. // J. of Coord. Chem. 2008. Vol. 61(4). P.499507.
51. Zhuojia Lin, Yang Li, Alexandra M. Z. Slawin and Russell E. Morris / Hydrogenbond-
directing effect in the ionothermal synthesis of metal coordination polymers .
// Dalton Trans. 2008. P.39893994.
52. Haiyan He, Fangna Dai, Aiping Xie, Xin To ng and Daofeng Sun / Three novel 3D
metalorganic frameworks with a 1D ladder, tube or chain as assembly units. //
Cryst. Eng. Comm. 2008. Vol. 10. P. 14291435.
53. T. J. Prior, D. Bradshaw, S. J. Teatb and M. J. Rosseinsky / Designed layer
assembly: a three-dimensional framework with 74% extra-framework volume by
connection of infinite two-dimensional sheets. // Chem. Commun. 2003. P.
500501.
54. Chaoying Gao, Shuxia Liu, Linhua Xie, Yuanhang Ren, Jianfang Cao and
Chunyan Sun / Design and construction of a microporous metalorganic
framework based on the pillared-layer motif. // Cryst. Eng. Comm. 2007. Vol.
9. P. 545547.
55. Abraham F. Jalbout , Xin-Hua Li , Mohammad R. Hassan, G. M. Golzar Hossain /
Construction of novel coordination polymers with simple ligands. // Trans. Met.
Chem. 2008. Vol. 33. P.597603.
56. Rong Cao, Qian Shi,Daofeng Sun, Maochun Hong, Wenghua Bi, and Yingjun
Zhao / Syntheses and Characterizations of Copper(II) Polymeric Complexes
Constructed from 1,2,4,5-Benzenetetracarboxylic Acid. // Inorg. Chem.. 2002.
Vol. 41(23). P. 61616168.
57. A. , . . . : , 1976. 541 .
58. Z. Arnold / Synthetische Reaktionen von Dimethylformamid. XVI. Formylierung
von -Picolin. // Collect. Czechosl. Chem. Commun. 1963. Vol. 28. P. 863-
868.
59. G. M. Sheldrick // Acta Cryst., Sect. A - 2008. V. 64. P. 112122.
60. K. Brandenburg / DIAMOND. Release 2.1e. // Crystal Impact GbR, Bonn,
Germany. - 1999.
105
61. Dolomano v O. V, Blake A. J., Champness N. R., Sc hröder M. / OLEX: new
software for visualization and analysis of extended crystal structures. // J. Appl.
Cryst. 2003. Vol.36.P.1283-1284.
62. Ibon Alkorta, José Elguero, Concepción Foces-Foces, and Lourdes Infantes /
Classification of hydrogen-bond motives in crystals of NH-pyrazoles: a mixed
empirical and theoretical approach. // ARKIVOC. 2006. (II). 15-30.
ISSN 1424-6376.
63. José Luis G. de Paz, José Elguero, Concepción Foces-Foces, Antonio L. Llamas-
Saiz, Francisco Aguilar-Parrilla, Olivier Klein and Hans-Heinrich Limbach /
Theoretical study of the structure and tautomerism of N1-unsubstituted pyrazoles
in the solid state. // J. Chem. Soc., Perkin Trans. 1997. Vol. 2. P. 101-109.
64. Sławomir J. Grabowski .- Hydrogen Bonding New Insights, - 2006, Springer.
65. Yen-Hsiang Liu, Huang-Chun Wu, Hsiu-Mei Lin,Wei-Hsien Hou and Kuang-Lieh
Lu / Crystal engineering toward intersecting channels in a interpenetrated
diamondoid network based on a net-to-net H-bonding interaction. // Chem.
Commun. 2003. P. 60-61.
66. Wells A.F. Structural inorganic chemistry. 5th Ed. Clarendon Press: Oxford,
1984.1382p., Wells A.F. Three-dimensional nets and polyhedra.Wiley
Interscience: New York.1977.268p.
67. Yan Xu, Li-Hua An and Lip-Lin Koh / Investigations into the Engineering of
Inorganic/Organic Solids: Hydrothermal Synthesis and Structure Characterization
of One-Dimensional Molybdenum Oxide Polymers. // Chem. Mater.,. 1996.
Vol. 8(4). P. 814818.
68. Deng et al. / Poly[propane-1,3-diammonium [tetra-l3-oxohexaoxotrimolybdenum(
VI)] dihydrate]. // Acta Cryst. 2007. C63. m256-
m258.
69. Klaus-Jürgen Range and Armin Fässler / Diammonium Trimolybdate(VI),
(NH4)2MO3O10. // Acta Cryst. 1990. C46. P.488-489.
70. Andrey B. Lysenko, Ganna A. Se nchyk, Jörg Lincke, Daniel Lässig, Andrey A.
Fokin, Ekaterina D. Butova, Peter R. Schreiner, Harald Krautscheid and
Konstantin V. Domasevitch / Metal oxide-organic frameworks (MOOFs), a new
106
series of coordination hybrids constructed from molybdenum(VI) oxide and
bitopic 1,2,4-triazole linkers // Dalton Trans. 2010. Vol. 39. P. 4223-4231.
71. Douglas Hagrman, Chloe Zubeita , Dr. David J. Rose, Prof. Jon Zubieta, Dr.
Robert C. Haushalter / Composite Solids Constructed From One- Dimensional
Coordination Polymer Matrices and Molybdenum Oxide Subunits :
Polyoxomolybdate Clusters within [{Cu(4,4'-bpy)}4Mo8O24] and [{Ni(H2 0)2(4,4'-
bpy)2}Mo8O24] and One-Dimensional Oxide Chains in [{Cu(4,4'-bpy)}4Mo15O47]
8 H2O // Angew. Chem. 1997. Vol. 36(8). P. 873876; Xu, L., Qin, C.,
Wang, X., Wei, Y.
& Wang, E. / Hydrothermal Synthesis and Structure of a New Helical Chain
Constructed from Only Molybdenum−Oxide Building Blocks // Inorg. Chem.
2003. Vol. 42. P. 7342-7344.; Xiao, D., An,
H., Wang, E. & Xu, L. / Syntheses and structures of two novel inorganicorganic
hybrid octamolybdates: [H2enMe]2[Mo8O26]2H2O and [Ni(2,2′-bpy)3]2[δ-Mo8O26]
// J. Mol. Struct. 2005. Vol. 738. P. 217-225.
72. Xue-Xiang Xu, Xiao-Zeng You, Xin Wang / The crystal structure of
tetra(piperidinium)octamolybdate(VI) tetrahydrate // Polyhedron. 1994. Vol.
13( 6-7). P.1011-1114.
73. Hoong-Kun Fun, Boon-Chuan Yip, Jing-Yang Niu and Xiao-Zeng You /
Tetrakis(triethylammonium) Octa- molybdate(VI) Dihydrate. // Acta Cryst.
1996. C52. P. 506-509.
74. Desiraju G.R. / Hydrogen bridges in crystal engineering: Interactions without
borders. // Acc. Chem. Res.2002.Vol. 37.P.565-573.
75. Isabel Ro zas, Ibo n Alkorta, and José Elguero / Bifurcate d Hydrogen Bonds:
Three-Centered Interactions // J. Phys. Chem. 1998. Vol. 102. P. 9925 9932.
76. G. A. Jeffrey. An Introduction to Hydrogen Bonding.- Oxford University Press,
Oxford, 1997.
77. Hunter C.A. and Sanders J.K.M. / The nature of ππ interactions. //
J.Amer.Chem.Soc. 1990. Vol.112. P.5525-5534.
78. M. A. Kiskin, G. G. Aleksandrov, Zh. V. Dobrokhotova, V. M. Novotortsev, Yu.
G. Shvedenkov, and I. L. Eremenko / Transformations of high spin MnII and FeII
polymeric pivalates in reactions with pivalic acid and o-phenylenediamines. //
107
Russian Chemical Bulletin, International Edition. 2006. Vol. 55(5). P. 806
820.
79. Olga M. Nazarenko, Julia A. Rusanova, Harald Krautscheid and KonstantinV.
Domasevitch / catena-Poly[thorium(IV)-tetrakis( μ-2-3-carboxyadamantane-1-
carboxylato)]: a quadruple helical strand driven by a synergy of coordination and
hydrogen bonding. // Acta Cryst. 2010. C66. m276m2.
80. D. J. Duchamp and R. E. Marsh / The crystal structure of trimesic acid (benzene-1,
3, 5 tricarboxylic acid). // Acta Crystallogr. 1969. Sect. B, Vol. 25(1). P. 5
19.
81. Michael J. Zaworotko / Superstructural diversity in two dimensions: crystal
engineering of laminated solids. // Chem. Comm. 2001. P.1-9.
82. Klaus Merz and Vera Vasylyeva / Development and boundaries in the field of
supramolecular synthons. // Cryst. Eng. Comm. 2010. Vol.12. P. 3989-4002.
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24.02.20

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24.02.20



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